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Essentials of Organic Chemistry : For Students of Pharmacy, Medicinal Chemistry and Biological Chemistry.

Author: Paul M Dewick
Publisher: Wiley, 2013.
Edition/Format:   eBook : Document : EnglishView all editions and formats
Summary:
Essentials of Organic Chemistry is an accessible introduction to the subject for students of Pharmacy, Medicinal Chemistry and Biological Chemistry. Designed to provide a thorough grounding in fundamental chemical principles, the book focuses on key elements of organic chemistry and carefully chosen material is illustrated with the extensive use of pharmaceutical and biochemical examples.<br /> <br /> In  Read more...
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Genre/Form: Electronic books
Additional Physical Format: Print version:
Dewick, Paul M.
Essentials of Organic Chemistry : For Students of Pharmacy, Medicinal Chemistry and Biological Chemistry.
: Wiley, ©2013
Material Type: Document, Internet resource
Document Type: Internet Resource, Computer File
All Authors / Contributors: Paul M Dewick
ISBN: 9781118681961 1118681967
OCLC Number: 1044713000
Notes: 6.1.4 Leaving groups.
Description: 1 online resource (952 pages)
Contents: Title Page ; Contents; Preface; 1 Molecular representations and nomenclature ; 1.1 Molecular representations; 1.2 Partial structures; 1.3 Functional groups; 1.4 Systematic nomenclature; 1.5 Common groups and abbreviations; 1.6 Common, non-systematic names; 1.7 Trivial names for complex structures; 1.8 Acronyms; 1.9 Pronunciation; 2 Atomic structure and bonding ; 2.1 Atomic structure; 2.2 Bonding and valency; 2.3 Atomic orbitals; 2.4 Electronic configurations; 2.5 Ionic bonding; 2.6 Covalent bonding; 2.6.1 Molecular orbitals: <U+0076> and <U+0073> bonds ; 2.6.2 Hybrid orbitals in carbon. 2.6.3 Hybrid orbitals in oxygen and nitrogen2.7 Bond polarity; 2.8 Conjugation; 2.9 Aromaticity; 2.9.1 Benzene; 2.9.2 Cyclooctatetraene; 2.9.3 Hückel's rule ; 2.9.4 Kekulé structures ; 2.9.5 Aromaticity and ring currents; 2.9.6 Aromatic heterocycles; 2.9.7 Fused rings; 2.10 Resonance structures and curly arrows; 2.11 Hydrogen bonding; 2.12 Molecular models; 3 Stereochemistry ; 3.1 Hybridization and bond angles; 3.2 Stereoisomers; 3.3 Conformational isomers; 3.3.1 Conformations of acyclic compounds; 3.3.2 Conformations of cyclic compounds; 3.4 Configurational isomers. 3.4.1 Optical isomers: chirality and optical activity3.4.2 Cahn-Ingold-Prelog system to describe configuration at chiral centres; 3.4.3 Geometric isomers; 3.4.4 Configurational isomers with several chiral centres; 3.4.5 Meso compounds; 3.4.6 Chirality without chiral centres; 3.4.7 Prochirality; 3.4.8 Separation of enantiomers: resolution; 3.4.9 Fischer projections; 3.4.10 D and L configurations ; 3.5 Polycyclic systems; 3.5.1 Spiro systems; 3.5.2 Fused ring systems; Box 3.18; 3.5.3 Bridged ring systems; 4 Acids and bases ; 4.1 Acid-base equilibria; 4.2 Acidity and pKa values. 4.3 Electronic and structural features that influence acidity4.3.1 Electronegativity; 4.3.2 Bond energies; 4.3.3 Inductive effects; 4.3.4 Hybridization effects; 4.3.5 Resonance/delocalization effects; 4.4 Basicity; 4.5 Electronic and structural features that influence basicity; 4.5.1 Electronegativity; 4.5.2 Inductive effects; 4.5.3 Hybridization effects; 4.5.4 Resonance/delocalization effects; 4.6 Basicity of nitrogen heterocycles; 4.7 Polyfunctional acids and bases; 4.8 pH; 4.9 The Henderson-Hasselbalch equation; 4.10 Buffers; 4.11 Using pKa values; 4.11.1 Predicting acid-base interactions. 4.11.2 Isotopic labelling using basic reagents4.11.3 Amphoteric compounds: amino acids; 4.11.4 pKa and drug absorption; 5 Reaction mechanisms ; 5.1 Ionic reactions; 5.1.1 Bond polarity; 5.1.2 Nucleophiles, electrophiles, and leaving groups; 5.2 Radical reactions; 5.3 Reaction kinetics and mechanism; 5.4 Intermediates and transition states; 5.5 Types of reaction; 5.6 Arrows; 6 Nucleophilic reactions: nucleophilic substitution ; 6.1 The SN2 reaction: bimolecular nucleophilic substitution; 6.1.1 The effect of substituents; 6.1.2 Nucleophiles: nucleophilicity and basicity; 6.1.3 Solvent effects.

Abstract:

Essentials of Organic Chemistry is an accessible introduction to the subject for students of Pharmacy, Medicinal Chemistry and Biological Chemistry. Designed to provide a thorough grounding in fundamental chemical principles, the book focuses on key elements of organic chemistry and carefully chosen material is illustrated with the extensive use of pharmaceutical and biochemical examples.<br /> <br /> In order to establish links and similarities the book places prominence on principles and deductive reasoning with cross-referencing. This informal text also places the main emphasis on understan.

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