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Ligand exchange chromatography

Author: Vadim A Davankov; James D Navratil; Harold F Walton
Publisher: Boca Raton : CRC Press, Taylor & Francis Group, 2018.
Series: CRC revivals.
Edition/Format:   eBook : Document : EnglishView all editions and formats
Summary:
"This book presents a systematic and comprehensive review of the information on chromatographic processes that involve the formation of coordination compounds, aiming not only to demonstrate the achievements that have been made in the theory of praxis of chromatography, but also to point out, as far as possible, the future of potential of ligand exchange chromatography."--Provided by publisher.
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Genre/Form: Electronic books
Additional Physical Format: Print version:
Material Type: Document, Internet resource
Document Type: Internet Resource, Computer File
All Authors / Contributors: Vadim A Davankov; James D Navratil; Harold F Walton
ISBN: 9781351074025 1351074024 9781351082471 1351082477 9781351099370 135109937X 1315894920 9781315894928 9781351090926 1351090925
OCLC Number: 1020789873
Notes: "First published 1988 by CRC Press"--Copyright page.
Description: 1 online resource : illustrations.
Contents: Intro --
Title Page --
Copyright Page --
Foreword --
The Authors --
Table of Contents --
Chapter 1 Introduction: History, Principles, Terminology --
References --
Chapter 2 Genral Considerations --
I. Experimental Conditions --
A. Metal Ions --
B. Exchangers --
C. Eluents and Detection --
D. Elution Orders --
II. Metal-Ligand Equilibria In Exchangers And Solutions --
III. Partition Of Nonionic Organic Compunds Between Exchangers And Solutions --
References --
Chapter 3 Separation Of Amines --
I. Introduction --
II. Aliphatic Amines --
III. Aromatic Amines --
IV. Aliphatic Diamines and Polyamines --
V. Aziridines, Alkanolamines, and Hydrazines --
VI. Amino Sugars --
VII. Alkaloids --
VIII. Miscellaneous Nitrogen-Containing Ligands --
References --
Chapter 4 Seperation Of Amino Acids, Peptides And Proteins --
I. Amino Acids And Peptides On Polymeric Sorbents --
II. Amino Acids And Peptides On Silica-Based Packings --
III. Metal Chelate Affinity Chromatography Of Proteins --
References --
Chapter 5 Separation Of Enantiomers --
I. Introduction And Background: Three-Point Interaction --
II. Chiral Stationary Phases --
A. Chiral Polymeric Ligand Exchangers --
1. Synthesis of Chiral Resins --
2. Chromatographic Resolution of Racemic Amino Acids --
B. Silica-Bonded Chiral Phases --
C. Coating of Silica With Chiral Ligands --
III. Chiral Complexes In The Mobile Phase --
IV. Mechanism of Chiral Recognition of Enantiomers --
V. Thermodynamics Of Formation Of Diastereomeric Sorption Complexes --
VI. Ligand Exchange In The Outer Coordination Sphere Of Stable Complexes --
VII. Separation Of Enantiomers By Gas Chromatography --
References --
Chapter 6 Nonnitrogen Ligands --
I. Sulphur Ligands --
II. Oxygen Ligands --
A. Carbohydrates And Polyhydroxy Compounds --
1. Method A --
2. Method B --
3. Method C --
4. Method D --
5. Method E. 6. Method F And The Techniques That Use Ligand Exchange --
B. Phenols --
C. Carboxylic Acids --
D. Miscellaneous Oxygen-Containing Ligands --
References --
Chapter 7 Metal-Olefin Complexes --
I. Metal-Olefin Complexes --
II. Miscellaneous Separations On Supported Metal Salts --
References --
Chapter 8 Conclusion --
Index.
Series Title: CRC revivals.
Responsibility: authors, Vadim A. Davankov, Institute of Organo-Element Compounds, Academy of Sciences of the U.S.S.R., Moscow, U.S.S.R., James D. Navratil, Professor, University of New South Wales, Kensington, New South Wales, Australia, Harold F. Walton, Department of Chemistry, University of Colorado, Boulder, Colorado.

Abstract:

"This book presents a systematic and comprehensive review of the information on chromatographic processes that involve the formation of coordination compounds, aiming not only to demonstrate the achievements that have been made in the theory of praxis of chromatography, but also to point out, as far as possible, the future of potential of ligand exchange chromatography."--Provided by publisher.

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