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Mathematical Theory of Sedimentation Analysis.

Author: Eric Hutchinson
Publisher: Elsevier Science, 2016.
Edition/Format:   eBook : Document : EnglishView all editions and formats
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Genre/Form: Electronic books
Material Type: Document, Internet resource
Document Type: Internet Resource, Computer File
All Authors / Contributors: Eric Hutchinson
ISBN: 1483274357 9781483274355
OCLC Number: 952667180
Description: 1 online resource
Contents: 2.20 The Extrapolation Procedures Due to Oth and Desreux --
Appendices --
References --
Chapter 3. Multicomponent Systems --
A. Relation between Refractive Index and Concentration --
3.1 Paucidisperse and Polydisperse Systems --
3.2 Expressions for the Refractive Index and Its Gradient --
B. Paucidisperse Systems --
3.3 Basic Equations for Three-Component Systems --
3.4 The Cose of Independent Sedimentation and Diffusion --
3.5 Evaluation of Weight Fractions --
3.6 The Equivalent Boundary Position --
3.7 The Johnston-Ogston Effect --
3.8 Extension of the Archibald Method to Multicomponent Systems --
C. Polydisperse Systems --
3.9 Distribution Functions --
3.10 Refractive Index Gradient Curves for Polydisperse Solutions --
3.11 The Case of Negligible Diffusion --
3.12 An Extrapolation Procedure for Obtaining ?(s) --
3.13 An Analysis for Gaussian Distributions --
3.14 Determination of D and p --
3.15 Extrapolation to Infinite Dilution --
3.16 Some Examples --
Appendices --
References --
Chapter 4. Chemically Reacting Systems --
A. Basic Equations --
4.1 Introduction --
4.2 Continuity Equations for Chemically Reacting Solutes --
4.3 Constituent Quantities --
B. Polymerization --
4.4 Methods for Determining Polymerization Constants --
4.5 Determination of Mw as a Function of c --
4.6 Integration of the Continuity Equations for Monomer-Polymer Systems --
4.7 Features of the Gradient Curves for Systems Involving Monomer-Polymer Equilibria --
4.8 The Case of Finite Rates of Association and Dissociation --
C. Isomerization --
4.9 Basic Equations --
4.10 Some Boundary Features of Isomer Systems --
D. Complex Formation --
4.11 The Solution of Gilbert and Jenkins for a Reacting System of the Type A + B{u21C6}AB --
4.12 Average Number of Small Molecules Bound to a Macromolecule --
Appendices --
References --
PART II: EQUILIBRIUM. Chapter 5. Sedimentation-Diffusion Equilibrium --
A. Introduction --
5.1 Sedimentation Equilibrium --
5.2 Basic Equations for the Sedimentation Equilibrium --
B. Two-Component Systems --
5.3 Integration of the Basic Differential Equation --
5.4 Virial Expansion for Sedimentation Equilibrium --
5.5 Corrections for Pressure --
C. Three-Component Systems --
5.6 Effects of Solvation --
5.7 Sedimentation Equilibrium in a Density Gradient --
D. Polymer Solutions --
5.8 Basic Equations and Assumptions --
5.9 Derivation of the Virial Expansion for Sedimentation Equilibrium --
5.10 Actual Procedure for Determining Mw and BSD --
5.11 Expressions with the Continuous Distribution of Molecular Weights --
5.12 Thermodynamic Ideality and the Theta Temperature --
E. Determination of the Molecular Weight Distribution --
5.13 Previous Theories --
5.14 Expressions for Average Molecular Weights --
5.15 A Method for Average Molecular Weights and Molecular Weight Distribution --
5.16 Average Molecular Weights --
5.17 Determination of the Function q(?) --
F. Other Problems --
5.18 Electrolyte Solutions --
Appendices --
References --
Chapter 6. Approach to Sedimentation Equilibrium --
6.1 Introductory Remarks --
6.2 Prediction of the Time Required to Reach Equilibrium --
6.3 Measurement of the Diffusion Coefficient from the Rate of Approach to Equilibrium --
6.4 Nazarian's Approach to the Determination of D --
6.5 Application of the Synthetic Boundary Cell --
References --
Author Index --
Subject Index.

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