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Metal oxide nanostructures chemistry : synthesis from aqueous solutions

Author: Jean-Pierre Jolivet
Publisher: Oxford : Oxford University Press, 2019.
Edition/Format:   eBook : Document : English : 2nd editionView all editions and formats
Summary:
An overview of metal oxide nanoparticle fabrication in aqueous solution.
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Genre/Form: Electronic books
Additional Physical Format: Print version:
Jolivet, Jean-Pierre.
Metal oxide nanostructures chemistry.
New York, NY : Oxford University Press, 2019
(DLC) 2018045235
(OCoLC)1057730998
Material Type: Document, Internet resource
Document Type: Internet Resource, Computer File
All Authors / Contributors: Jean-Pierre Jolivet
ISBN: 9780190928124 0190928123
OCLC Number: 1080190676
Notes: Translation of the French language edition of: De la solution à l'oxyde, 2e edition : chimie aqueuse des cations métalliques, synthèse de nanostructures (2015).
Description: 1 online resource
Contents: Cover; Metal Oxide Nanostructures Chemistry; Copyright; Contents; Preface; List of Abbreviations; 1. Nanomaterials: Specificities of Properties and Synthesis; 1.1 Specific Properties of Nanoparticles; 1.1.1 Volume Effects; 1.1.2 Surface Effects; 1.1.3 The Influence of Size Effect on Thermodynamic, Structure, and Reactivity of Oxide Nanoparticles; 1.2 Specificity and Requirements in the Fabrication Methods of Nanoparticles; 2. Water and Metal Cations in Solution; 2.1 Water as Solvent, Physicochemistry of the Liquid; 2.1.1 Electronic Structure of the Water Molecule 2.1.2 Structure of Liquid Water2.1.3 Hydration of Ions and Structure of Solutions; 2.1.4 Water under Hydrothermal Conditions; 2.2 Acidity and Cation Speciation; 2.3 Mechanisms of Hydroxylation and Redox Reactions in Solution; 2.4 Evaluation of Partial Charges on Atoms in Combination; 2.4.1 Ionocovalency and Partial Charges; 2.4.2 Electronegativity; 2.4.3 Partial Charges Model; 3. Condensation in Solution: Polycations and Polyanions; 3.1 Hydroxylation and Condensation of Cations; 3.1.1 Mechanisms and Structural Considerations; 3.1.2 The Different Behaviors of Cations Against Condensation 3.2 Olation: Formation of Polycations3.2.1 Mechanisms and Structural Considerations; 3.2.2 Chromium III Polycations; 3.3 Oxolation: Formation of Polyanions; 3.3.1 Elements of the p-​Block; 3.3.2 Transition Elements under High Oxidation States: Polyoxometalates; 4. Precipitation: Structures and Mechanisms; 4.1 The Formation of Solids: Thermodynamics and Crystal Structure; 4.1.1 Divalent Elements; 4.1.2 Layered Double Hydroxides; 4.1.3 Trivalent Elements; 4.1.4 Tetra-​ and Pentavalent Elements; 4.1.5 Transition Elements under High Oxidation States; 4.1.6 Summary; 4.1.7 Polymetallic Oxides 4.2 Kinetics of Precipitation and Mechanisms of Crystallization4.2.1 The Steps in the Formation of a Solid; 4.2.2 Nucleation and Growth: Energetics and Dynamics; 4.2.3 Mechanisms of Crystallization: Structural and Morphological Evolution of Oxide Nanoparticles in Suspension; 4.2.4 Effect of Microwave Heating on Crystallization in Solution; 5. Surface Chemistry and Physicochemistry of Oxides; 5.1 The Oxide-​Solution Interface; 5.1.1 Origin of the Electrostatic Surface Charge; 5.1.2 Surface Acidity: Multisite Complexation Modeling; 5.2 Solvation and Structure of the Solid-​Solution Interface 5.2.1 Solvation of Particles5.2.2 Surface-​Electrolyte Interactions; 5.3 Stability of Nanoparticle Dispersions Against Aggregation; 5.3.1 Van der Waals Forces; 5.3.2 Electrostatic Forces; 5.3.3 Total Potential Energy of the Interaction; 5.4 Surface Reactivity: Adsorption; 5.4.1 Electrostatic Interactions, Outer-​Sphere Surface Complexes; 5.4.2 Specific Interactions: Inner-​Sphere Surface Complexes; 5.4.3 Adsorption and Transfers Through the Oxide-​Solution Interface; 5.4.4 Adsorption and Surface Energy: Role of Acidity in Particle Size and Morphology
Other Titles: De la solution à l'oxyde.
Responsibility: Jean-Pierre Jolivet.

Abstract:

This book is a much-needed new edition of Jolivet's work, last published in 2000. It introduces the most recent concepts and modelings such as dynamics of particle growth, ordered aggregation, ionic  Read more...

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