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Metal oxides in heterogeneous catalysis

Author: Jacques C Védrine; G S Korotchenkov
Publisher: Amsterdam Elsevier [2018] ©2018
Series: Metal oxides series; Metal oxides series.
Edition/Format:   Print book : Document   Computer File : English
Summary:
Metal Oxides in Heterogeneous Catalysis is an overview of the past, present and future of heterogeneous catalysis using metal oxides catalysts. The book presents the historical, theoretical, and practical aspects of metal oxide-based heterogeneous catalysis. Metal Oxides in Heterogeneous Catalysis deals with fundamental information on heterogeneous catalysis, including reaction mechanisms and kinetics  Read more...
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Additional Physical Format: ebook version :
Material Type: Document
Document Type: Book, Computer File
All Authors / Contributors: Jacques C Védrine; G S Korotchenkov
ISBN: 9780128116319 0128116315 0128116323 9780128116326
OCLC Number: 1041108562
Description: xxi, 596 pages : illustrations (some color)
Contents: Machine generated contents note: 1. Fundamentals of heterogeneous catalysis / Jacques C. Vedrine --
1.1. Introduction to catalysis --
1.2. Some historical features of industrial applications of catalysis --
1.3. Solid catalysts, inorganic chemistry and material science --
1.4. Catalyst activity --
1.5. Kinetics and reaction mechanisms in heterogeneous catalysis --
1.6. Active sites in heterogeneous catalysis --
1.7. Deactivation by cocking or poisoning and regeneration --
1.8. Main physical techniques used to characterise catalysts and reaction intermediates --
1.9. Theoretical approach and calculations on oxide based heterogeneous catalysts --
1.10. Concluding remarks --
References --
2. Synthesis of metal oxide catalysts / Eric Marceau --
2.1. Introduction --
2.2. Simple oxides --
2.3. Mixed oxides --
2.4. Supported catalysts --
2.5. Conclusion and perspectives --
References --
3. Nanoporous oxide catalysts: A new catalyst paradigm of SYNGAS production for sustainable energy and environmental applications / Jacques C. Vedrine --
3.1. Introduction --
3.2. Conversion routes of methane to syngas --
3.3. Syngas, catalysis, and sustainability --
3.4. Syngas from DRM --
3.5. Syngas from POM --
3.6. Syngas from SRM --
3.7. Conclusions --
Acknowledgments --
References --
4. Catalysts and catalysis for acid --
base reactions / Yoshio Ono --
4.1. Roles of acid sites and base sites in acid- and base-catalyzed reactions --
4.2. Characterization of acid and base sites --
4.3. Catalysis by solid acid catalysts --
4.4. Catalysis by solid base catalysts --
4.5. Solid acid catalysts --
4.6. Solid base catalysts --
4.7. Perspectives in acid and base catalysis --
References --
5. Gas phase heterogeneous partial oxidation reactions / Benjamin Solsona --
5.1. Principles of catalyst choice for selective oxidation reactions and historical aspects --
5.2. Nature of active sites in selective oxidation reactions --
5.3. Structural features of metal oxide catalysts for oxidation reactions --
5.4. Selective oxidation and ODH of short chain alkanes --
5.5. Propene oxidation on Bi-molybdate based catalysts --
5.6. Butane direct oxidation to maleic anhydride on VPO type catalysts --
5.7. Propane direct oxidation/ammoxidation on mixed MoVTe(Sb)Nb --
O catalysts --
5.8. Trends in partial oxidation processes --
References --
Further reading --
6. Transition metal oxides for combustion and depollution processes / Daniel Duprez --
6.1. Introduction --
6.2. Overview on the mechanisms of total oxidation reactions over metal oxides --
6.3. Oxidation of carbon monoxide --
6.4. Methane oxidation --
6.5. Other hydrocarbons and oxygenates --
6.6. Oxidation of chlorine- and sulfur-containing compounds --
6.7. Oxidation of automotive soots --
6.8. Nitrogen-containing compounds --
6.9. Wet air oxidation --
6.10. Conclusions and perspectives --
References --
7. Photocatalytic water splitting on metal oxide-based semiconductor photocatalysts / Can Li --
7.1. Introduction --
7.2. Typical metal oxide-based semiconductor for photocatalytic water splitting --
7.3. Strategies to improve the photocatalytic performance of photocatalysts --
7.4. Conclusions and prospectives --
References --
8. Main industrial processes using metal oxides as catalysts or support and future trends in heterogeneous catalysis --
8.1. Acrolein oxidation to acrylic acid, preparation of industrial catalysts / Jean-Luc Dubois --
8.1.1. Introduction: Industry and Academic publications --
key players --
8.1.2. Reaction conditions, reactors and reactor loading --
8.1.3. Catalyst shape --
8.1.4. Safety and flammability limits --
8.1.5. Effect of steam partial pressure --
8.1.6. Reaction mechanism --
8.1.7. Economic importance of selectivity --
8.1.8. Catalyst physical testing --
8.1.9. Reactor loading --
8.1.10. Catalyst preparation --
8.1.11. Catalyst production quality control --
8.1.12. Catalyst activity testing and characterization --
8.1.13. Improvements on catalyst preparation and perspectives --
8.1.14. Conclusions and perspectives --
References --
8.2. Selective oxidation in industry: Applications of metal oxides in the petrochemical industry / James F. Brazdil --
8.2.1. Introduction --
8.2.2. Ammoxidation catalysts --
8.2.3. Oxidation catalysts --
8.2.4. Conclusions, perspectives and future directions --
Acknowledgments --
References --
8.3. Industrial applications of metal oxide catalysts --
an impressive past and a promising future / Thomas F. Degnan --
8.3.1. Introduction --
8.3.2. Industrial metal oxide catalyst systems --
8.3.3. Metal oxide processes --
8.3.4. Conclusions --
References --
Further reading --
9. Concluding remarks and challenges of heterogeneous catalysis on metal oxides / Jacques C. Vedrine --
9.1. Sustainability --
9.2. Efficiency --
9.3. Oil refining, energy and transport --
9.4. Hydrogen --
9.5. Gaseous noxious emissions --
9.6. Greenhouse gases --
9.7. Current trends in applied heterogeneous catalysis --
9.8. New catalysts --
9.9. Biocatalysis --
9.10. Photocatalysis --
9.11. Main topics to be studied in the future --
9.12. General conclusions --
References.
Series Title: Metal oxides series; Metal oxides series.
Responsibility: edited by Jacques C. Vedrine, series editor Ghenadii Korotcenkov.

Abstract:

Metal Oxides in Heterogeneous Catalysis is an overview of the past, present and future of heterogeneous catalysis using metal oxides catalysts. The book presents the historical, theoretical, and practical aspects of metal oxide-based heterogeneous catalysis. Metal Oxides in Heterogeneous Catalysis deals with fundamental information on heterogeneous catalysis, including reaction mechanisms and kinetics approaches.There is also a focus on the classification of metal oxides used as catalysts, preparation methods and touches on zeolites, mesoporous materials and Metal-organic frameworks (MOFs) in catalysis. It will touch on acid or base-type reactions, selective (partial) and total oxidation reactions, and enzymatic type reactions The book also touches heavily on the biomass applications of metal oxide catalysts and environmentally related/depollution reactions such as COVs elimination, DeNOx, and DeSOx. Finally, the book also deals with future trends and prospects in metal oxide-based heterogeneous catalysis.

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