• Cite/Export
  Cite/Export

  Copy a citation

  APA (6th ed.)

  

  Chicago (Author-Date, 15th ed.)

  

  Harvard (18th ed.)

  

  MLA (7th ed.)

  

  Turabian (6th ed.)

  

  Export a citation

  Export to RefWorks   Export to EndNote / Reference Manager   Export to EasyBib
  Export to EndNote / Reference Manager(non-Latin)   Cancel

  Note: Citations are based on reference standards. However, formatting rules can vary widely between applications and fields of interest or study. The specific requirements or preferences of your reviewing publisher, classroom teacher, institution or organization should be applied.
• Print
• E-mail
  E-mail

  All fields are required.

  The E-mail Address(es) field is required. Please enter recipient e-mail address(es).

  The E-mail Address(es) you entered is(are) not in a valid format. Please re-enter recipient e-mail address(es).

  You may send this item to up to five recipients.

  Enter recipient e-mail address(es): Separate up to five addresses with commas (,)

  The name field is required. Please enter your name.

  Enter your name: The subject field is required. Please enter the subject. Subject:

  The E-mail message field is required. Please enter the message.

  E-mail Message: I thought you might be interested in this item at http://www.worldcat.org/oclc/1051832577 Title: Metal sulfide: An efficient promoter for the synthesis of 2-mercaptobenzothiazoles from 2-haloanilines and carbon disulfide. Author: Tianmiao Zhang; Weijing Qin; Ning Zhu; Limin Han; Liubo Wang; Hailong Hong Publisher: Philadelphia, Pa : Taylor & Francis Group, 2017. ISBN/ISSN: 0039-7911 OCLC:1051832577

  
  

  Please verify that you are not a robot.

  Cancel
• Share
• Permalink
  Permalink

  Copy this URL to link to this page:

Metal sulfide: An efficient promoter for the synthesis of 2-mercaptobenzothiazoles from 2-haloanilines and carbon disulfide.

Author:	Tianmiao Zhang; Weijing Qin; Ning Zhu; Limin Han; Liubo Wang; All authors
Publisher:	Philadelphia, Pa : Taylor & Francis Group, 2017.
Edition/Format:	Downloadable article : Document  Computer File : English
Publication:	Synthetic communications
Summary:	ABSTRACT: A convenient method has been developed for the preparation of a variety of 2-mercaptobenzothiazoles from 2-haloanilines and CS2 mediated by metal sulfide. In this reaction, 2-haloanilines reacted with CS2 in the presence of Na2 S · 9H2 O to form 2-mercaptobenzothiazoles. Na2 S · 9H2 O functioned both as an activator of CS2 and as a base. Furthermore, NMR analysis was used to identify the different reaction mechanisms of 2-haloanilines and CS2 mediated by Na2 S or 1, 8-diazabicyclo[5.4.0]undec-7-ene (DBU), which demonstrated that Na2 S interacted only with CS2, while DBU reacted with both 2-iodoaniline and CS2 . GRAPHICAL ABSTRACT  Read more...
Subjects	Organic compounds Synthesis Chemistry, Organic
More like this	Similar Items