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Metallomacrocycles : from structures to applications

Author: Haibo Yang
Publisher: Cambridge, England : Royal Society of Chemistry, [2019] ©2019
Series: Monographs in supramolecular chemistry, no. 27.
Edition/Format:   eBook : Document : EnglishView all editions and formats
Summary:
A comprehensive overview of metallomacrocycles from designing complex functional metallosupramolecular systems to their applications.
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Genre/Form: Electronic books
Additional Physical Format: Print version:
Metallomacrocycles.
Cambridge, England : Royal Society of Chemistry, [2019]
(OCoLC)1036730227
Material Type: Document, Internet resource
Document Type: Internet Resource, Computer File
All Authors / Contributors: Haibo Yang
ISBN: 9781788013123 1788013123
OCLC Number: 1057283976
Description: 1 online resource : illustrations.
Contents: Cover; Metallomacrocycles: From Structures to Applications; Preface; Contents; Chapter 1 --
Evolution of Metallomacrocycles From Macrocycles; 1.1 Macrocycles; 1.2 Coordination-driven Self-assembly; 1.3 Two-dimensional Assembly of Metallomacrocycles; 1.4 Characterization of Metallomacrocycles; 1.4.1 Mass Spectrometry; 1.4.2 X-ray Measurement; 1.5 The Essential Characteristic of Metallomacrocycles; 1.5.1 Charged Systems; 1.5.2 The Dynamic Characteristic of Metallomacrocycles; 1.6 Conclusion and Outlook; Acknowledgements; References. Chapter 2 --
Design Principles of Self-assembled Metallomacrocycles2.1 Introduction; 2.2 The Directional-bonding Approach; 2.2.1 Molecular Rhomboids; 2.2.2 Molecular Triangles; 2.2.3 Molecular Squares; 2.2.4 Molecular Hexagons; 2.3 The Symmetry-interaction Approach; 2.4 The Weak-link Approach; 2.5 Conclusion; Acknowledgements; References; Chapter 3 --
Self-organization in Coordination-driven Self-assembled Metallomacrocyles; 3.1 Introduction; 3.2 Two-component Self-organization Systems; 3.3 Three-component Self-organization Systems; 3.4 Multicomponent Self-organization Systems; 3.5 Conclusion. AcknowledgementsReferences; Chapter 4 --
Self-assembled Chiral Metallomacrocycles; 4.1 Introduction; 4.2 Synthetic Strategies for Self-assembled Chiral Metallomacrocycles; 4.2.1 Introduction of Chiral Bridging Ligands; 4.2.2 Use of Chiral Metal Auxiliaries that Possess Chiral Capping Groups; 4.2.3 Use of Inherently Chiral Metal Centres Having Specific Coordination Geometries; 4.3 Applications of Self-assembled Chiral Metallomacrocycles; 4.3.1 Chiral Sensing; 4.3.2 Asymmetric Catalysis; 4.4 Conclusions; Acknowledgements; References. Chapter 5 --
Half-sandwich Iridium- and Rhodium-based Organometallic MacrocyclesReferences; Chapter 6 --
Supramolecular Transformations of Metallomacrocycles; 6.1 Introduction; 6.2 Supramolecular Transformations Between Metallomacrocycles and One-dimensional Metallosupramolecular Polymers; 6.3 Supramolecular Transformations Between Metallomacrocycles and Another Two-dimensional Metallomacrocycles; 6.4 Supramolecular Transformations Between Metallomacrocycles and 3D Metallocages; 6.5 Conclusion; Acknowledgements; References. Chapter 7 --
Coordination-driven Self-assembly of Functionalized Self-assembled Metallomacrocycles7.1 Introduction; 7.1.1 Sites of Functionalization; 7.1.2 Pre- versus Post-self-assembly; 7.2 Photophysical Properties; 7.2.1 Introduction; 7.2.2 Covalently Append Dyes; 7.2.3 Sensor Applications; 7.2.4 Effects of Functional Groups on Photophysical Properties; 7.2.5 BODIPY-functionalized Metallomacrocycles; 7.3 Electrochemically Active Materials; 7.3.1 Introduction; 7.3.2 Functionalization with dppf Ligands; 7.3.3 Covalently Tethered Ferrocene; 7.3.4 Fc/Dendrimer Hybrid Materials.
Series Title: Monographs in supramolecular chemistry, no. 27.
Responsibility: edited by Hai-Bo Yang.

Abstract:

A comprehensive overview of metallomacrocycles from designing complex functional metallosupramolecular systems to their applications.  Read more...

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