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Pericyclic Chemistry : Orbital Mechanisms and Stereochemistry

Author: Dipak K Mandal
Publisher: Amsterdam, Netherlands : Elsevier, [2018] ©2018
Edition/Format:   eBook : Document : EnglishView all editions and formats
Summary:
"Pericyclic Chemistry: Orbital Mechanisms and Stereochemistry is a complete guide to the topic that is ideal for graduate students, advanced undergraduate students and researchers in organic chemistry. An introduction to molecular orbital theory and relevant stereochemical concepts is provided as background, with all four classes of pericyclic reactions discussed and illustrated with orbital picture representations.  Read more...
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Genre/Form: Electronic books
Additional Physical Format: (OCoLC)1004837271
Material Type: Document, Internet resource
Document Type: Internet Resource, Computer File
All Authors / Contributors: Dipak K Mandal
ISBN: 9780128149591 0128149590
OCLC Number: 1029759755
Description: 1 online resource.
Contents: 1. Molecular Orbitals 2. Stereochemical concepts 3. Pericyclic reactions: Introduction, classification and the Woodward-Hoffmann rules 4. Cycloadditions 1: Perturbation theory of reactivity, regioselectivity and periselectivity 5. Cycloadditions 2: Stereochemistry of [4+2] and [2+2] cycloadditions 6. Cycloadditions 3: Cheletropic, higher order and multicomponent cycloadditions 7. Electrocyclic reactions: Stereochemistry and torquoselectivity 8. Sigmatropic rearrangements 1: [1,j] Shifts 9. Sigmatropic rearrangements 2: [i,j] Shifts 10. Group transfer reactions 11. Correlation diagrams
Responsibility: Dipak K. Mandal.

Abstract:

"Pericyclic Chemistry: Orbital Mechanisms and Stereochemistry is a complete guide to the topic that is ideal for graduate students, advanced undergraduate students and researchers in organic chemistry. An introduction to molecular orbital theory and relevant stereochemical concepts is provided as background, with all four classes of pericyclic reactions discussed and illustrated with orbital picture representations. Also included are chapters on cycloadditions, the most versatile class, and electrocyclic reactions, sigmatropic rearrangements and group transfer reactions. A separate chapter on the construction of correlation diagrams is also included, emphasizing a practical, hands on approach. Author Dipak Kumar Mandal brings over 30 years of teaching experience to the topic and illuminates pericyclic chemistry with a clear and fresh perspective. Comprehensive guide featuring unifying mechanistic approaches, stereochemical details and novel rules and mnemonics to delineate product stereochemistryIncludes two background chapters on molecular orbitals and stereochemical conceptsEmphasizes a theoretical understanding using perturbation theory (Salem-Klopman equation) and physical insights from orbital and state correlation analyses"--

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