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Polymerization of ethylene : from free radical homopolymerization to hybrid radical / catalytic copolymerization

Author: Etienne GrauChristophe BoissonVincent MonteilRoger SpitzLaurent BonneviotAll authors
Publisher: 2010.
Dissertation: Thèse de doctorat : Chimie : Lyon 1 : 2010.
Edition/Format:   Computer file : Document : Thesis/dissertation : English
Summary:
Ce travail concerne l'étude de la polymérisation de l'éthylène allant de l'homopolymérisation purement radicalaire jusqu'à la copolymérisation utilisant un mécanisme hybride radicalaire/catalytique. Ce travail montre que le polyéthylène peut être synthétisé par voie radicalaire dans des conditions expérimentales beaucoup plus douces que celles utilisées industriellement (P>1000 bar et T>100°C).
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Genre/Form: Thèses et écrits académiques
Material Type: Document, Thesis/dissertation, Internet resource
Document Type: Internet Resource, Computer File
All Authors / Contributors: Etienne Grau; Christophe Boisson; Vincent Monteil; Roger Spitz; Laurent Bonneviot; Krzysztof Matyjaszewski; Stéphane Mecking; Sylvain Marque; Michel Glotin; Université Claude Bernard (Lyon).; École Doctorale de Chimie (Lyon).; Laboratoire de Chimie, Catalyse, Polymères et Procédés.
OCLC Number: 919562827
Notes: Titre provenant de l'écran-titre.
Description: 1 online resource
Responsibility: Etienne Grau ; sous la direction de Christophe Boisson et de Vincent Monteil et de Roger Spitz.

Abstract:

Ce travail concerne l'étude de la polymérisation de l'éthylène allant de l'homopolymérisation purement radicalaire jusqu'à la copolymérisation utilisant un mécanisme hybride radicalaire/catalytique. Ce travail montre que le polyéthylène peut être synthétisé par voie radicalaire dans des conditions expérimentales beaucoup plus douces que celles utilisées industriellement (P>1000 bar et T>100°C). L'éthylène a été polymérisé à partir de 10°C et 5 bar de pression d'éthylène. Un important effet activateur du solvant a été mis en évidence. De plus la polymérisation en milieu dispersé aqueux de l'éthylène a aussi été étudiée. Des latex stables de PE avec des taux de solide de 40% ont pu être obtenus. Deux morphologies de nanoparticules, cylindre ou sphère, ont été observées. La copolymérisation radicalaire avec des monomères vinyliques polaires a été également étudiée en solution ou en émulsion. Des insertions d'éthylène jusqu'à 50% ont été obtenues. De plus l'influence du comonomère et du solvant organique utilisé sur la polymérisation radicalaire de l'éthylène a été quantifiée. Une nouvelle technique de polymérisation hybride radicalaire/catalytique a été développée pour pouvoir obtenir toute la gamme de compositions possibles de copolymères éthylène/monomère polaire à partir d'un complexe de nickel qui amorce la polymérisation radicalaire et catalyse également la polymérisation de l'éthylène. Ce complexe subit une rupture homolytique réversible de la liaison nickel carbone et permet la synthèse de copolymères multiblocs. Des insertions d'éthylène de 1% à 99% ont été obtenues en faisant varier la pression d'éthylène et la concentration en comonomères polaires.

This work aims to study ethylene polymerization from the free radical polymerization process to the copolymerization by a hybrid radical/catalytic mechanism. PE is synthesized by free radical polymerization under milder experimental conditions than industrial ones (P>1000 bar and T>100°C). Indeed free radical polymerization of ethylene is efficient even down to pressure of 5 bar and temperature of 10°C. Several unexpected behaviors are observed such as a high solvent activation effect. Beside the slurry process in organic solvent, polymerization in aqueous dispersed media is also performed. Stable PE latexes are obtained with solid contents up to 40%. Two different PE particles morphologies are observed cylinder-like and sphere-like. Then free radical copolymerization is studied using a broad range of polar vinyl monomers in organic solvent and emulsion. Insertions up to 50% of ethylene are obtained under mild conditions. The ambivalent role of comonomer as monomer and activator of the polymerization is highlighted. In order to obtain a wide range of composition of polar/non-polar copolymers a new technique of polymerization has been developed. A nickel complex is used to initiate the free radical polymerization and to catalyse the coordination/insertion ethylene polymerization. This nickel complex is capable of a reversible homolytic cleavage of its nickel-carbon bond. Finally, this hybrid process is used to copolymerize efficiently ethylene with various polar vinyl monomers. Multiblock copolymers with ethylene content from 1% to 99% are obtained by simply varying the monomer feeds.

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Primary Entity<\/h3>\n
<http:\/\/www.worldcat.org\/oclc\/919562827<\/a>> # Polymerization of ethylene : from free radical homopolymerization to hybrid radical \/ catalytic copolymerization<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nbgn:ComputerFile<\/a>, schema:CreativeWork<\/a>, schema:MediaObject<\/a>, bgn:Thesis<\/a> ;\u00A0\u00A0\u00A0\nbgn:inSupportOf<\/a> \"Th\u00E8se de doctorat : Chimie : Lyon 1 : 2010.<\/span>\" ;\u00A0\u00A0\u00A0\nlibrary:oclcnum<\/a> \"919562827<\/span>\" ;\u00A0\u00A0\u00A0\nlibrary:placeOfPublication<\/a> <http:\/\/id.loc.gov\/vocabulary\/countries\/fr<\/a>> ;\u00A0\u00A0\u00A0\nschema:about<\/a> <http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Thing\/polymerisation_radicalaire<\/a>> ; # Polym\u00E9risation radicalaire<\/span>\n\u00A0\u00A0\u00A0\nschema:about<\/a> <http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Topic\/hautes_pressions<\/a>> ; # Hautes pressions<\/span>\n\u00A0\u00A0\u00A0\nschema:about<\/a> <http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Topic\/catalyse<\/a>> ; # Catalyse<\/span>\n\u00A0\u00A0\u00A0\nschema:about<\/a> <http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Thing\/emulsion<\/a>> ; # Emulsion<\/span>\n\u00A0\u00A0\u00A0\nschema:about<\/a> <http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Thing\/copolymerisation<\/a>> ; # Copolym\u00E9risation<\/span>\n\u00A0\u00A0\u00A0\nschema:about<\/a> <http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Topic\/polyaddition<\/a>> ; # Polyaddition<\/span>\n\u00A0\u00A0\u00A0\nschema:about<\/a> <http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Topic\/ethylene<\/a>> ; # \u00C9thyl\u00E8ne<\/span>\n\u00A0\u00A0\u00A0\nschema:about<\/a> <http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Thing\/monomere_polaire<\/a>> ; # Monom\u00E8re polaire<\/span>\n\u00A0\u00A0\u00A0\nschema:about<\/a> <http:\/\/dewey.info\/class\/547.7\/<\/a>> ;\u00A0\u00A0\u00A0\nschema:about<\/a> <http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Thing\/haute_pression<\/a>> ; # Haute pression<\/span>\n\u00A0\u00A0\u00A0\nschema:about<\/a> <http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Thing\/ethylene<\/a>> ; # Ethyl\u00E8ne<\/span>\n\u00A0\u00A0\u00A0\nschema:author<\/a> <http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Person\/grau_etienne_1983<\/a>> ; # Etienne Grau<\/span>\n\u00A0\u00A0\u00A0\nschema:contributor<\/a> <http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Person\/spitz_roger<\/a>> ; # Roger Spitz<\/span>\n\u00A0\u00A0\u00A0\nschema:contributor<\/a> <http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Person\/monteil_vincent_1975<\/a>> ; # Vincent Monteil<\/span>\n\u00A0\u00A0\u00A0\nschema:contributor<\/a> <http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Person\/matyjaszewski_krzysztof_1950<\/a>> ; # Krzysztof Matyjaszewski<\/span>\n\u00A0\u00A0\u00A0\nschema:contributor<\/a> <http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Person\/boisson_christophe_19<\/a>> ; # Christophe Boisson<\/span>\n\u00A0\u00A0\u00A0\nschema:contributor<\/a> <http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Organization\/universite_claude_bernard_lyon<\/a>> ; # Universit\u00E9 Claude Bernard (Lyon).<\/span>\n\u00A0\u00A0\u00A0\nschema:contributor<\/a> <http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Person\/marque_sylvain_1976<\/a>> ; # Sylvain Marque<\/span>\n\u00A0\u00A0\u00A0\nschema:contributor<\/a> <http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Organization\/ecole_doctorale_de_chimie_lyon<\/a>> ; # \u00C9cole Doctorale de Chimie (Lyon).<\/span>\n\u00A0\u00A0\u00A0\nschema:contributor<\/a> <http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Person\/bonneviot_laurent<\/a>> ; # Laurent Bonneviot<\/span>\n\u00A0\u00A0\u00A0\nschema:contributor<\/a> <http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Person\/mecking_stephane_19<\/a>> ; # St\u00E9phane Mecking<\/span>\n\u00A0\u00A0\u00A0\nschema:contributor<\/a> <http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Person\/glotin_michel<\/a>> ; # Michel Glotin<\/span>\n\u00A0\u00A0\u00A0\nschema:contributor<\/a> <http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Organization\/laboratoire_de_chimie_catalyse_polymeres_et_procedes<\/a>> ; # Laboratoire de Chimie, Catalyse, Polym\u00E8res et Proc\u00E9d\u00E9s.<\/span>\n\u00A0\u00A0\u00A0\nschema:datePublished<\/a> \"2010<\/span>\" ;\u00A0\u00A0\u00A0\nschema:description<\/a> \"Ce travail concerne l\'\u00E9tude de la polym\u00E9risation de l\'\u00E9thyl\u00E8ne allant de l\'homopolym\u00E9risation purement radicalaire jusqu\'\u00E0 la copolym\u00E9risation utilisant un m\u00E9canisme hybride radicalaire\/catalytique. Ce travail montre que le poly\u00E9thyl\u00E8ne peut \u00EAtre synth\u00E9tis\u00E9 par voie radicalaire dans des conditions exp\u00E9rimentales beaucoup plus douces que celles utilis\u00E9es industriellement (P>1000 bar et T>100\u00B0C). L\'\u00E9thyl\u00E8ne a \u00E9t\u00E9 polym\u00E9ris\u00E9 \u00E0 partir de 10\u00B0C et 5 bar de pression d\'\u00E9thyl\u00E8ne. Un important effet activateur du solvant a \u00E9t\u00E9 mis en \u00E9vidence. De plus la polym\u00E9risation en milieu dispers\u00E9 aqueux de l\'\u00E9thyl\u00E8ne a aussi \u00E9t\u00E9 \u00E9tudi\u00E9e. Des latex stables de PE avec des taux de solide de 40% ont pu \u00EAtre obtenus. Deux morphologies de nanoparticules, cylindre ou sph\u00E8re, ont \u00E9t\u00E9 observ\u00E9es. La copolym\u00E9risation radicalaire avec des monom\u00E8res vinyliques polaires a \u00E9t\u00E9 \u00E9galement \u00E9tudi\u00E9e en solution ou en \u00E9mulsion. Des insertions d\'\u00E9thyl\u00E8ne jusqu\'\u00E0 50% ont \u00E9t\u00E9 obtenues. De plus l\'influence du comonom\u00E8re et du solvant organique utilis\u00E9 sur la polym\u00E9risation radicalaire de l\'\u00E9thyl\u00E8ne a \u00E9t\u00E9 quantifi\u00E9e. Une nouvelle technique de polym\u00E9risation hybride radicalaire\/catalytique a \u00E9t\u00E9 d\u00E9velopp\u00E9e pour pouvoir obtenir toute la gamme de compositions possibles de copolym\u00E8res \u00E9thyl\u00E8ne\/monom\u00E8re polaire \u00E0 partir d\'un complexe de nickel qui amorce la polym\u00E9risation radicalaire et catalyse \u00E9galement la polym\u00E9risation de l\'\u00E9thyl\u00E8ne. Ce complexe subit une rupture homolytique r\u00E9versible de la liaison nickel carbone et permet la synth\u00E8se de copolym\u00E8res multiblocs. Des insertions d\'\u00E9thyl\u00E8ne de 1% \u00E0 99% ont \u00E9t\u00E9 obtenues en faisant varier la pression d\'\u00E9thyl\u00E8ne et la concentration en comonom\u00E8res polaires.<\/span>\" ;\u00A0\u00A0\u00A0\nschema:description<\/a> \"This work aims to study ethylene polymerization from the free radical polymerization process to the copolymerization by a hybrid radical\/catalytic mechanism. PE is synthesized by free radical polymerization under milder experimental conditions than industrial ones (P>1000 bar and T>100\u00B0C). Indeed free radical polymerization of ethylene is efficient even down to pressure of 5 bar and temperature of 10\u00B0C. Several unexpected behaviors are observed such as a high solvent activation effect. Beside the slurry process in organic solvent, polymerization in aqueous dispersed media is also performed. Stable PE latexes are obtained with solid contents up to 40%. Two different PE particles morphologies are observed cylinder-like and sphere-like. Then free radical copolymerization is studied using a broad range of polar vinyl monomers in organic solvent and emulsion. Insertions up to 50% of ethylene are obtained under mild conditions. The ambivalent role of comonomer as monomer and activator of the polymerization is highlighted. In order to obtain a wide range of composition of polar\/non-polar copolymers a new technique of polymerization has been developed. A nickel complex is used to initiate the free radical polymerization and to catalyse the coordination\/insertion ethylene polymerization. This nickel complex is capable of a reversible homolytic cleavage of its nickel-carbon bond. Finally, this hybrid process is used to copolymerize efficiently ethylene with various polar vinyl monomers. Multiblock copolymers with ethylene content from 1% to 99% are obtained by simply varying the monomer feeds.<\/span>\" ;\u00A0\u00A0\u00A0\nschema:exampleOfWork<\/a> <http:\/\/worldcat.org\/entity\/work\/id\/2611422444<\/a>> ;\u00A0\u00A0\u00A0\nschema:genre<\/a> \"Th\u00E8ses et \u00E9crits acad\u00E9miques<\/span>\" ;\u00A0\u00A0\u00A0\nschema:inLanguage<\/a> \"en<\/span>\" ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Polymerization of ethylene : from free radical homopolymerization to hybrid radical \/ catalytic copolymerization<\/span>\" ;\u00A0\u00A0\u00A0\nschema:productID<\/a> \"919562827<\/span>\" ;\u00A0\u00A0\u00A0\nschema:url<\/a> <http:\/\/www.theses.fr\/2010LYO10242\/document<\/a>> ;\u00A0\u00A0\u00A0\nschema:url<\/a> <https:\/\/tel.archives-ouvertes.fr\/tel-01228981<\/a>> ;\u00A0\u00A0\u00A0\nwdrs:describedby<\/a> <http:\/\/www.worldcat.org\/title\/-\/oclc\/919562827<\/a>> ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n\n

Related Entities<\/h3>\n
<http:\/\/dewey.info\/class\/547.7\/<\/a>>\u00A0\u00A0\u00A0\u00A0a \nschema:Intangible<\/a> ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Organization\/ecole_doctorale_de_chimie_lyon<\/a>> # \u00C9cole Doctorale de Chimie (Lyon).<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Organization<\/a> ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"\u00C9cole Doctorale de Chimie (Lyon).<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Organization\/laboratoire_de_chimie_catalyse_polymeres_et_procedes<\/a>> # Laboratoire de Chimie, Catalyse, Polym\u00E8res et Proc\u00E9d\u00E9s.<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Organization<\/a> ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Laboratoire de Chimie, Catalyse, Polym\u00E8res et Proc\u00E9d\u00E9s.<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Organization\/universite_claude_bernard_lyon<\/a>> # Universit\u00E9 Claude Bernard (Lyon).<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Organization<\/a> ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Universit\u00E9 Claude Bernard (Lyon).<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Person\/boisson_christophe_19<\/a>> # Christophe Boisson<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Person<\/a> ;\u00A0\u00A0\u00A0\nschema:birthDate<\/a> \"19..<\/span>\" ;\u00A0\u00A0\u00A0\nschema:deathDate<\/a> \"\" ;\u00A0\u00A0\u00A0\nschema:familyName<\/a> \"Boisson<\/span>\" ;\u00A0\u00A0\u00A0\nschema:givenName<\/a> \"Christophe<\/span>\" ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Christophe Boisson<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Person\/bonneviot_laurent<\/a>> # Laurent Bonneviot<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Person<\/a> ;\u00A0\u00A0\u00A0\nschema:familyName<\/a> \"Bonneviot<\/span>\" ;\u00A0\u00A0\u00A0\nschema:givenName<\/a> \"Laurent<\/span>\" ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Laurent Bonneviot<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Person\/glotin_michel<\/a>> # Michel Glotin<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Person<\/a> ;\u00A0\u00A0\u00A0\nschema:familyName<\/a> \"Glotin<\/span>\" ;\u00A0\u00A0\u00A0\nschema:givenName<\/a> \"Michel<\/span>\" ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Michel Glotin<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Person\/grau_etienne_1983<\/a>> # Etienne Grau<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Person<\/a> ;\u00A0\u00A0\u00A0\nschema:birthDate<\/a> \"1983<\/span>\" ;\u00A0\u00A0\u00A0\nschema:deathDate<\/a> \"\" ;\u00A0\u00A0\u00A0\nschema:familyName<\/a> \"Grau<\/span>\" ;\u00A0\u00A0\u00A0\nschema:givenName<\/a> \"Etienne<\/span>\" ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Etienne Grau<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Person\/marque_sylvain_1976<\/a>> # Sylvain Marque<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Person<\/a> ;\u00A0\u00A0\u00A0\nschema:birthDate<\/a> \"1976<\/span>\" ;\u00A0\u00A0\u00A0\nschema:deathDate<\/a> \"\" ;\u00A0\u00A0\u00A0\nschema:familyName<\/a> \"Marque<\/span>\" ;\u00A0\u00A0\u00A0\nschema:givenName<\/a> \"Sylvain<\/span>\" ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Sylvain Marque<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Person\/matyjaszewski_krzysztof_1950<\/a>> # Krzysztof Matyjaszewski<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Person<\/a> ;\u00A0\u00A0\u00A0\nschema:birthDate<\/a> \"1950<\/span>\" ;\u00A0\u00A0\u00A0\nschema:deathDate<\/a> \"\" ;\u00A0\u00A0\u00A0\nschema:familyName<\/a> \"Matyjaszewski<\/span>\" ;\u00A0\u00A0\u00A0\nschema:givenName<\/a> \"Krzysztof<\/span>\" ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Krzysztof Matyjaszewski<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Person\/mecking_stephane_19<\/a>> # St\u00E9phane Mecking<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Person<\/a> ;\u00A0\u00A0\u00A0\nschema:birthDate<\/a> \"19..<\/span>\" ;\u00A0\u00A0\u00A0\nschema:deathDate<\/a> \"\" ;\u00A0\u00A0\u00A0\nschema:familyName<\/a> \"Mecking<\/span>\" ;\u00A0\u00A0\u00A0\nschema:givenName<\/a> \"St\u00E9phane<\/span>\" ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"St\u00E9phane Mecking<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Person\/monteil_vincent_1975<\/a>> # Vincent Monteil<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Person<\/a> ;\u00A0\u00A0\u00A0\nschema:birthDate<\/a> \"1975<\/span>\" ;\u00A0\u00A0\u00A0\nschema:deathDate<\/a> \"\" ;\u00A0\u00A0\u00A0\nschema:familyName<\/a> \"Monteil<\/span>\" ;\u00A0\u00A0\u00A0\nschema:givenName<\/a> \"Vincent<\/span>\" ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Vincent Monteil<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Person\/spitz_roger<\/a>> # Roger Spitz<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Person<\/a> ;\u00A0\u00A0\u00A0\nschema:familyName<\/a> \"Spitz<\/span>\" ;\u00A0\u00A0\u00A0\nschema:givenName<\/a> \"Roger<\/span>\" ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Roger Spitz<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Thing\/copolymerisation<\/a>> # Copolym\u00E9risation<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Thing<\/a> ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Copolym\u00E9risation<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Thing\/emulsion<\/a>> # Emulsion<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Thing<\/a> ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Emulsion<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Thing\/ethylene<\/a>> # Ethyl\u00E8ne<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Thing<\/a> ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Ethyl\u00E8ne<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Thing\/haute_pression<\/a>> # Haute pression<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Thing<\/a> ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Haute pression<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Thing\/monomere_polaire<\/a>> # Monom\u00E8re polaire<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Thing<\/a> ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Monom\u00E8re polaire<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Thing\/polymerisation_radicalaire<\/a>> # Polym\u00E9risation radicalaire<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Thing<\/a> ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Polym\u00E9risation radicalaire<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Topic\/catalyse<\/a>> # Catalyse<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Intangible<\/a> ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Catalyse<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Topic\/ethylene<\/a>> # \u00C9thyl\u00E8ne<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Intangible<\/a> ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"\u00C9thyl\u00E8ne<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Topic\/hautes_pressions<\/a>> # Hautes pressions<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Intangible<\/a> ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Hautes pressions<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/2611422444#Topic\/polyaddition<\/a>> # Polyaddition<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Intangible<\/a> ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Polyaddition<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/id.loc.gov\/vocabulary\/countries\/fr<\/a>>\u00A0\u00A0\u00A0\u00A0a \nschema:Place<\/a> ;\u00A0\u00A0\u00A0\ndcterms:identifier<\/a> \"fr<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/www.theses.fr\/2010LYO10242\/document<\/a>>\u00A0\u00A0\u00A0\nrdfs:comment<\/a> \"Acc\u00E8s au texte int\u00E9gral<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/www.worldcat.org\/title\/-\/oclc\/919562827<\/a>>\u00A0\u00A0\u00A0\u00A0a \ngenont:InformationResource<\/a>, genont:ContentTypeGenericResource<\/a> ;\u00A0\u00A0\u00A0\nschema:about<\/a> <http:\/\/www.worldcat.org\/oclc\/919562827<\/a>> ; # Polymerization of ethylene : from free radical homopolymerization to hybrid radical \/ catalytic copolymerization<\/span>\n\u00A0\u00A0\u00A0\nschema:dateModified<\/a> \"2020-04-18<\/span>\" ;\u00A0\u00A0\u00A0\nvoid:inDataset<\/a> <http:\/\/purl.oclc.org\/dataset\/WorldCat<\/a>> ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n\n

Content-negotiable representations<\/p>\n