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S-Block Metal Complexes

Author: Matthias Westerhausen
Publisher: [Place of publication not identified] MDPI AG - Multidisciplinary Digital Publishing Institute, 2017.
Edition/Format:   eBook : Document
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Genre/Form: Electronic book
Material Type: Document, Internet resource
Document Type: Internet Resource, Computer File
All Authors / Contributors: Matthias Westerhausen
ISBN: 9783038425892 3038425893
OCLC Number: 1048161204
Notes: Title from content provider.
Description: 1 online resource
Responsibility: Matthias Westerhausen.

Abstract:

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Dear Colleagues, The coordination chemistry of the s-block metals spans diverse fields, ranging from shielded coordination compounds over hydride to organometallic complexes for diverse applications. New developments pertain, not only to the lithium and magnesium chemistry with inspiring examples, such as heterobimetallic or heteroleptic complexes with special reactivity patterns, but the heavy s-block metals have progressively gained attention in various fields. Subvalent magnesium(I) derivatives are increasingly being used for reduction reactions, turbo-Grignard reagents show enhanced reactivity and tolerance toward functional groups, hydrides act as hydrogen storage materials, heavy Grignard reagents are available by straight forward procedures--just to name a few examples. Quantum chemical calculations deal with unique bonding situations and the relevance of d-orbital participation has been discussed to understand structure-reactivity relationships. Especially the complexes of the heavy alkaline earth metals are catalytically active in diverse reactions, promoting hydrofunctionalization reactions and Lewis acid catalysis. This Special Issue aims to highlight the structural and chemical diversity of s-block metal complexes, as well as the broad field of applications. Prof. Dr. Matthias Westerhausen Guest Editor.

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